2-[({[Bis(pyridin-2-yl)methylidene]hydrazinecarbonyl}hydrazinylidene)(pyridin-2-yl)methyl]pyridinium tetrafluoroborate

Crystal structure of bromo(2,2':6',2"-terpyridine)(2-(phenylazo)-pyridine)ruthenium(II) tetrafluoroborate.

The title compound, C26H20N6BrRu(BF4), crystallizes in the centrosymmetric space group P2(1)/n and consists of discrete complex units. The Ru(II) ion is octahedrally coordinated to one 2,2':6',2"-terpyridine (tpy), one 2-(phenylazo)pyridine (azpy) and a Br atom in trans-axial position at a distance of 2.547(5)A. The shorter Ru-N (azo) distance (1.960(3)A) than the Ru-N(py) distance (2.061(3)A) ...

An unexpected reaction of 2-alkynylaryldiazonium tetrafluoroborate with sulfur dioxide.

An unexpected result from the reaction of 2-alkynylaryldiazonium tetrafluoroborate with sulfur dioxide is described. In the presence of morpholin-4-amine, this transformation catalyzed by copper(i) bromide proceeds through insertion of sulfur dioxide and intramolecular 5-endo cyclization, leading to benzo[b]thiophene 1,1-dioxides in moderate to good yields.

تعیین غلظت کریپتوفیکس 2، 2، 2 در رادیوداروی [18F]FDG

غلظت کریپتوفیکس 2،2،2 در محلول‌های [18F]FDG و استانداردهای کریپتوفیکس 2،2،2 به دو روش آشکارسازی (ترکیب کریپتوفیکس 2،2،2) با بخار ید و معرف یدوپلاتینات تعیین شد. در هر دو روش، تفاوت غلظت محلول‌های کریپتوفیکس، به صورت تفاوت در شدت رنگ لکه‌های آشکار شده بر روی TLC نمایان شد. حد تشخیص کریپتوفیکس با بخار ید و معرف یدوپلاتیتات به ترتیب ppm25 و ppm2 می‌باشد. هر دو روش را می‌توان برای پذیرش ...

Cover vol.2, no.2 October 2005

6 Concluding Remarks 5.2 Incorporate Database Categorization 5 Improving the Retrieval of Relevant Documents = 2:0m 2 2 2 2 2 2 2 2 2 2 2 = 2:0m 2 2 2 2 2 2 2 2 2 2 2

In this paper, we proposed a new, highly scalable method to solve the database selection problem when the number of local databases in a metasearch engine is very large. For single-term queries, this method guarantees all desired documents to be retrieved. Experiments were conducted to show that this method is very eeective for typical short Internet queries. We also illustrated that the our da...